| Slackware is quite UNIX-like, I'm told. I don't know exactly what UNIX-like entails, but most distros are probably acceptable.
As far as installing on an external HD, it depends on whether you intend to boot from this HD, or boot from an internal HD. If an internal, you simply need to add an entry in your bootloader for the external HD. If you plan to boot from the external HD, it's probably a simple matter of making sure that the BIOS has the boot order correct.
As far as apps, OpenOffice has already been recommended for word processing. I'd recognize BMP for audio, MPlayer for video, Firefox obviously, Gaim for IM'ing.
If you intend to use a terminal a lot, you may want a more customizable terminal as well. I personally use Eterm and love it, but there are lots of choices out there.
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