My pc runs automated scripts on a server \\someserver\*.vb

a couple of questions:

1) how can i discover other servers my box accesses and cat them to a file?
2) how can i block \\somepath and when typed is routed to similar to HOST files for local DNS? This way the scripts can't be accessed anymore.
3) how can i intercept vbs scripts before executed and maybe cancel its execution? vbscript.dll